Thermally induced electron transfer in a CsCoFe Prussian blue derivative:: The specific role of the alkali-metal ion

被引：89

作者：

Bleuzen, A

Escax, V

Ferrier, A

Villain, F

Verdaguer, M

Münsch, P

Itié, JP

机构：

[1] Univ Paris 06, CNRS, UMR 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

[2] Univ Paris 11, MENRS, CNRS,CEA, UMR 130,Lab PUtilisat Rayonnement Electromagnet, F-91898 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 28期

关键词：

electron transfer; Prussian blue analogues; spin crossover; X-ray absorption spectroscopy; X-ray diffractions;

D O I：

10.1002/anie.200460086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A central role for the alkali metal cation was determined in the thermally activated electron transfer CoIII(LS)-FeII(LS) ⇋ CoII(HS)-FeIII(LS) in a CsCoFe Prussian blue derivative by localizing the alkali metal ion and identifying its interactions with the surrounding network in the high- and low-temperature states (see scheme).

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页码：3728 / 3731

页数：4

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