Synthesis of nitrones using the methyltrioxorhenium hydrogen peroxide system

被引:112
作者
Murray, RW [1 ]
Iyanar, K [1 ]
Chen, JX [1 ]
Wearing, JT [1 ]
机构
[1] PULP & PAPER RES INST CANADA,VANCOUVER LAB,VANCOUVER,BC V6S 2L9,CANADA
关键词
D O I
10.1021/jo961252e
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Secondary amines are oxidized by the methyltrioxorhenium/hydrogen peroxide system to the corresponding nitrones in excellent yield. The results provide a further example of the parallel between the chemistry of this metal system and that of the dioxiranes.
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页码:8099 / 8102
页数:4
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