First observation of the circular dichroism spectra of chiral subphthalocyanines with C3 symmetry

被引：39

作者：

Kobayashi, N ^{[1
]}

Nonomura, T ^{[1
]}

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 23期

关键词：

macrocycles; subphthalocyanines; resolution; circular dichroism;

D O I：

10.1016/S0040-4039(02)00773-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Subphthalocyanines (SubPc) with C-3 symmetry due to peripheral tri-nitro and tert-butyl groups have been resolved using an optically active HPLC column, and their circular dichroism (CD) spectra, which show a mirror-image relationship with respect to the line of [theta]=0, recorded as the first example of the CD spectra of SubPcs. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4253 / 4255

页数：3

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