Organofluoro-silica xerogels as high-performance optical oxygen sensors

被引:21
作者
Ciriminna, Rosaria [1 ]
Pagliaro, Mario [1 ]
机构
[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, Italy
关键词
CARBON-DIOXIDE; CHEMICAL SENSORS; MATRICES; GLASS; GAS;
D O I
10.1039/b819417c
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Ubiquitous oxygen (O-2) is one of the most important analytes to be assessed in medicine, industry and the environment. Due to a number of advantages, miniaturized optical sold-gel sensors are rapidly replacing older electrochemical sensors. This account provides an overview of fluorinated organically modified silicate (ORMOSIL) xerogels as optical chemical sensors and shows how, together with the dye quenching rate, the subtle structural features of an organofluoro-silica matrix is of fundamental importance in determining the overall sensor performance.
引用
收藏
页码:1531 / 1535
页数:5
相关论文
共 18 条
[1]   Probes and polymers for optical sensing of oxygen [J].
Amao, Y .
MICROCHIMICA ACTA, 2003, 143 (01) :1-12
[2]   O2-responsive chemical sensors based on hybrid xerogels that contain fluorinated precursors [J].
Bukowski, Rachel M. ;
Davenport, Michael D. ;
Titus, Albert H. ;
Bright, Frank V. .
APPLIED SPECTROSCOPY, 2006, 60 (09) :951-957
[3]   High-performance quenchometric oxygen sensors based on fluorinated xerogels doped with [Ru(dpp)3]2+ [J].
Bukowski, RM ;
Ciriminna, R ;
Pagliaro, M ;
Bright, FV .
ANALYTICAL CHEMISTRY, 2005, 77 (08) :2670-2672
[4]   Fiber-optic carbon dioxide sensor based on fluorinated xerogels doped with HPTS [J].
Chu, Chen-Shane ;
Lo, Yu-Lung .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 129 (01) :120-125
[5]   High-performance fiber-optic oxygen sensors based on fluorinated xerogels doped with Pt(II) complexes [J].
Chu, Chen-Shane ;
Lo, Yu-Lung .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 124 (02) :376-382
[6]   The grounds for the activity of TPAP in oxidation catalysis in supercritical carbon dioxide when confined in hybrid fluorinated silica matrices [J].
Fidalgo, Alexandra ;
Ciriminna, Rosaria ;
Ilharco, Laura M. ;
Campestrini, Sandro ;
Carraro, Massimo ;
Pagliaro, Mario .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (15) :2026-2032
[7]  
LACKOWICZ JR, 1999, PRINCIPLES FLUORESCE, pCH8
[8]   Porphyrin-doped sol-gel glass as a probe for oxygen sensing [J].
Lee, SK ;
Okura, I .
ANALYTICA CHIMICA ACTA, 1997, 342 (2-3) :181-188
[9]   ORGANICALLY MODIFIED SOL-GEL SENSORS [J].
LEV, O ;
TSIONSKY, M ;
RABINOVICH, L ;
GLEZER, V ;
SAMPATH, S ;
PANKRATOV, I ;
GUN, J .
ANALYTICAL CHEMISTRY, 1995, 67 (01) :A22-A30
[10]   Dye-doped organically modified silica glass for fluorescence based carbon dioxide gas detection [J].
Malins, C ;
MacCraith, BD .
ANALYST, 1998, 123 (11) :2373-2376