High-yield electro-oxidative preparation of graphene oxide

被引：62

作者：

Abdelkader, A. M. ^{[1
,2
]}

Kinloch, I. A. ^{[1
]}

Dryfe, R. A. W. ^{[2
]}

机构：

[1] Univ Manchester, Sch Mat, Manchester M13 9PL, Lancs, England

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 61期

基金：

英国工程与自然科学研究理事会;

关键词：

GRAPHITE OXIDE; FUNCTIONALIZED GRAPHENE; NANOSHEETS; DISPERSIONS; EXFOLIATION; REDUCTION; PAPER;

D O I：

10.1039/c4cc03260h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report a green electrochemical oxidative approach to convert large quantities of graphite into graphene oxide (GO). The resulted GO flakes have been characterized using various analytical techniques. It was possible to control the degree of oxidation of the produced GO via controlling the electrochemical parameters of the process.

引用

页码：8402 / 8404

页数：3

共 25 条

[1] Continuous Electrochemical Exfoliation of Micrometer-Sized Graphene Using Synergistic Ion Intercalations and Organic Solvents [J].

Abdelkader, Amr M. ;

Kinloch, Ian A. ;

Dryfe, Robert A. W. .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (03) :1632-1639

[2]

Brodie B. C., 1859, PHILOS T R SOC LONDO, V149, P249, DOI [10.1098/rspl.1859.0007, DOI 10.1098/RSTL.1859.0013]

[3] Self-Assembled Free-Standing Graphite Oxide Membrane [J].

Chen, Chengmeng ;

Yang, Quan-Hong ;

Yang, Yonggang ;

Lv, Wei ;

Wen, Yuefang ;

Hou, Peng-Xiang ;

Wang, Maozhang ;

Cheng, Hui-Ming .

ADVANCED MATERIALS, 2009, 21 (29) :3007-3011

[4] Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications [J].

Chen, Da ;

Feng, Hongbin ;

Li, Jinghong .

CHEMICAL REVIEWS, 2012, 112 (11) :6027-6053

[5] Single stage electrochemical exfoliation method for the production of few-layer graphene via intercalation of tetraalkylammonium cations [J].

Cooper, Adam J. ;

Wilson, Neil R. ;

Kinloch, Ian A. ;

Dryfe, Robert A. W. .

CARBON, 2014, 66 :340-350

[6] Preparation and characterization of graphene oxide paper [J].

Dikin, Dmitriy A. ;

Stankovich, Sasha ;

Zimney, Eric J. ;

Piner, Richard D. ;

Dommett, Geoffrey H. B. ;

Evmenenko, Guennadi ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

NATURE, 2007, 448 (7152) :457-460

[7] The chemistry of graphene oxide [J].

Dreyer, Daniel R. ;

Park, Sungjin ;

Bielawski, Christopher W. ;

Ruoff, Rodney S. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240

[8] A One-Step, Solvothermal Reduction Method for Producing Reduced Graphene Oxide Dispersions in Organic Solvents [J].

Dubin, Sergey ;

Gilje, Scott ;

Wang, Kan ;

Tung, Vincent C. ;

Cha, Kitty ;

Hall, Anthony S. ;

Farrar, Jabari ;

Varshneya, Rupal ;

Yang, Yang ;

Kaner, Richard B. .

ACS NANO, 2010, 4 (07) :3845-3852

[9] A new structural model for graphite oxide [J].

He, HY ;

Klinowski, J ;

Forster, M ;

Lerf, A .

CHEMICAL PHYSICS LETTERS, 1998, 287 (1-2) :53-56

[10] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

← 1 2 3 →