Gram-Scale Synthesis of Cu2O Nanocubes and Subsequent Oxidation to CuO Hollow Nanostructures for Lithium-Ion Battery Anode Materials

被引：623

作者：

Park, Ji Chan ^{[1
,2
]}

Kim, Jeonghan ^{[3
]}

Kwon, Hyuksong ^{[3
]}

Song, Hyunjoon ^{[1
,2
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea

[3] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 07期

关键词：

SOLUTION-PHASE SYNTHESIS; CO OXIDATION; COPPER-OXIDE; SHAPE EVOLUTION; SOLUTION ROUTE; NANOPARTICLES; NANOCRYSTALS; CATALYSTS; CU(OH)(2); GROWTH;

D O I：

10.1002/adma.200800596

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A procedure for gram-scale synthesis of monodisperse Cu2O nanocubes; by a simple polyol process is demonstrated. The nanocubes are subsequently oxidized to form CuO hollow cubes, spheres, and urchin-like particles, through a sequential dissolution-precipitation process. The CuO urchin-like particles exhibited excellent electrochemical performance and stability, superior to those of hollow structures, for lithium-ion battery anode materials.

引用

页码：803 / +

页数：6

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