Synthesis and efficient purification of cyclic poly (dimethylsiloxane)

被引:17
作者
White, BM
Watson, WP
Barthelme, EE
Beckham, HW [1 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Sch Text & Fiber Engn, Atlanta, GA 30332 USA
关键词
D O I
10.1021/ma0255027
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis and efficient purification of cyclic poly(dimethylsiloxane) (PDMS) was reported. A modification to the synthetic method was proposed which allowed effective separation of linear byproducts from the cyclic polymer on the basis of their chemical differences. Mass spectrometry showed that all linear anionic species were removed by ion-exchange reactions using a macroporous anion-exchange resin.
引用
收藏
页码:5345 / 5348
页数:4
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