Polyhedral oligomeric silsesquioxanes: A new class of amphiphiles at the air/water interface

被引：81

作者：

Deng, JJ

Polidan, JT

Hottle, JR

Farmer-Creely, CE

Viers, BD

Esker, AR ^{[1
]}

机构：

[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

[2] USAF, ERC, Res Labs, Edwards AFB, CA 93524 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 51期

关键词：

D O I：

10.1021/ja027860v

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Insoluble films of trisilanolisobutyl-POSS and octaisobutyl-POSS at the air/water interface are investigated by means of surface pressure - area per molecule isotherm (Π - A) and Brewster angle microscopy (BAM). Analysis of the experimental results shows the partial cage molecule, trisilanolisobutyl-POSS, is a surface-active molecule that self-assembles into uniform monolayer upon compression; but the fully condensed cage molecule, octaisobutyl-POSS, is nonamphiphilic. Copyright © 2002 American Chemical Society.

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页码：15194 / 15195

页数：2

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