Reaction-temperature-dependent supramolecular isomerism of coordination networks based on the organometallic building block [Cu2I(μ2-BQ)(μ2-OAc)2]

被引：219

作者：

Masaoka, S ^{[1
]}

Tanaka, D ^{[1
]}

Nakanishi, Y ^{[1
]}

Kitagawa, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 19期

关键词：

coordination polymers; polymorphism; quinines; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three supramolecular isomers, [Cu2I(μ4- BQ)(μ2-OAc)2]n (α phase), [Cu 2I(μ3-BQ)(μ2-OAc) (μ3-OAc)]n (β phase), and [Cu2 I(μ2-BQ)(μ3-OAc)2] n (γ phase), were crystallized by using the organometallic building block shown, which has two types of supramolecular synthon. Interestingly, these three supramolecular isomers were crystallized from the same solvent. BQ = benzoquinone.

引用

页码：2530 / 2534

页数：5

共 17 条

[1]

[Anonymous], 1995, ANGEW CHEM, V107, P2541

[2] Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2 (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)) [J].