A novel 3D brick-wall coordination network based on nodes with square-pyramidal connectivity

被引:54
作者
Oh, M [1 ]
Carpenter, GB [1 ]
Sweigart, DA [1 ]
机构
[1] Brown Univ, Dept Chem, Providence, RI 02912 USA
关键词
coordination polymers; polymers; quinones self-assembly; supramolecular;
D O I
10.1002/anie.200250637
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular brickwork: Acetate-bridged dimeric copper(II) units (blue) are linked by [η4-benzoquinone)Mn(CO)3]- organometalloligands (O, red) in a squarepyramidal fashion to afford a metalorganometallic coordination network having an unprecedented 3D brick architecture.
引用
收藏
页码:2026 / 2028
页数:3
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