Polybis(1-methyl-2-thioimidazolate)iron(II):: Crystal structure and magnetic properties of a one-dimensional material exhibiting ferromagnetic ordering below 8 K

被引：13

作者：

Rettig, SJ ^{[1
]}

Sánchez, V ^{[1
]}

Storr, A ^{[1
]}

Thompson, RC ^{[1
]}

Trotter, J ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 25期

关键词：

D O I：

10.1021/ic990774k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal Structure and Magnetic Properties of a One-Dimensional Material Exhibiting Ferromagnetic Ordering below 8 K. The title compound has a rodlike 1-D structure in which iron ions are double bridged by 1-methyl-2-thioimidazolate ligands and the metal chromophores alternate along the chain between FeS4 and FeN4. Antiferromagnetic intrachain coupling with spin canting generates residual spin on the chains that undergo long-range ferromagnetic order below 8 K.

引用

页码：5920 / +

页数：5

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