Piperazinediium bis(pyridine-2,6-dicarboxylato)-cuprate(II) tetrahydrate

被引:28
作者
Aghabozorg, Hossein
Zabihi, Fatemeh
Ghadermazi, Mohammad
Gharamaleki, Jafar Attar
Sheshmani, Shabnam
机构
[1] Teacher Training Univ, Dept Chem, Tehran 15614, Iran
[2] Islamic Azad Univ, Dept Chem, Shahre Rey Branch, Tehran, Iran
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806030297
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The reaction of copper(II) nitrate with the proton- transfer compound piperazinediium pyridine- 2,6- dicarboxylate, or (pipzH(2))(pydc), in aqueous solution leads to the formation of the title compound, (C4H12N2)[Cu(C7H3NO4)(2)]center dot 4H(2)O. The title compound is a six- coordinate complex with a distorted octahedral geometry around the central atom. In the crystal structure, a wide range of non- covalent interactions consisting of hydrogen bonding and pi-pi stacking connect the various components into a supramolecular structure.
引用
收藏
页码:M2091 / M2093
页数:3
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