Selective production of cyclic carbonate over polycarbonate using a double metal cyanide-quaternary ammonium salt catalyst system

被引：83

作者：

Dharman, Manju Mamparambath ^{[1
]}

Yu, Jeong-In ^{[1
]}

Ahn, Ji-Yeon ^{[1
]}

Park, Dae-Won ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem Engn, Pusan 609735, South Korea

来源：

GREEN CHEMISTRY | 2009年 / 11卷 / 11期

关键词：

DIOXIDE/ETHYLENE OXIDE MIXTURE; PROPYLENE-OXIDE; ETHYLENE CARBONATE; CHEMICAL FIXATION; COUPLING REACTION; DIOXIDE; COPOLYMERIZATION; ZINC; EPOXIDES; CO2;

D O I：

10.1039/b916875n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A double metal cyanide complex, an efficient catalyst for the copolymerization of CO2 with epoxide, was successfully utilized for the cycloaddition of CO2 to various epoxides in the presence of quaternary ammonium salts without any solvents.

引用

页码：1754 / 1757

页数：4

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