Controlling the surface composition of poly(3,4-ethylene dioxythiophene)poly(styrene sulfonate) blends by heat treatment

被引:45
作者
Jukes, PC
Martin, SJ
Higgins, AM
Geoghegan, M
Jones, RAL
Langridge, S
Wehrum, A
Kirchmeyer, S
机构
[1] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England
[2] Rutherford Appleton Lab, ISIS Div, Didcot OX11 0QX, Oxon, England
[3] Cambrige Display Technol, Cambridge CB3 0TX, England
[4] HC Stacck GMBH, Res & Dev, D-51368 Leverkusen, Germany
关键词
D O I
10.1002/adma.200306487
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(3,4 ethylene dioxythiophene)/ poly(styrene sulfonate) (PEDT/PSS) blends are widely used in organic light-emitting diodes (OLEDs) to enhance their performance. Using neutron reflectometry to study such blends, it is shown that substantial segregation of the blend components occurs at the surface (see Figure), a result that will have implications both for the performance and for the stability of optoelectronic devices using PEDT/PSS.
引用
收藏
页码:807 / +
页数:6
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