Recent advances in the kinetics of reversible addition fragmentation chain-transfer polymerization

被引：61

作者：

Vana, P ^{[1
]}

Quinn, JF ^{[1
]}

Davis, TP ^{[1
]}

Barner-Kowollik, C ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 6-7期

关键词：

D O I：

10.1071/CH02042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of complex molecular architectures with low polydispersities by reversible addition fragmentation chain-transer (RAFT) polymerization renders this process of high synthetic utility. Mechanistic and kinetic studies, however, are lacking. The authors here probed the process for long-lived intermediates (see Fig.), the results of which suggested that a stable polymeric radical sink exists.

引用

页码：425 / +

页数：8

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