Morphology-photovoltaic property correlation in perovskite solar cells: One-step versus two-step deposition of CH3NH3PbI3

被引:381
作者
Im, Jeong-Hyeok [1 ,2 ]
Kim, Hui-Seon [1 ,2 ]
Park, Nam-Gyu [1 ,2 ]
机构
[1] Sungkyunkwan Univ, Sch Chem Engn, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
来源
APL MATERIALS | 2014年 / 2卷 / 08期
基金
新加坡国家研究基金会;
关键词
ORGANOMETAL HALIDE PEROVSKITES; LOW-COST; RECOMBINATION; TRANSPORT;
D O I
10.1063/1.4891275
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Perovskite CH3NH3PbI3 light absorber is deposited on the mesoporous TiO2 layer via one-step and two-step coating methods and their photovoltaic performances are compared. One-step coating using a solution containing CH3NH3I and PbI2 shows average power conversion efficiency (PCE) of 7.5%, while higher average PCE of 13.9% is obtained from two-step coating method, mainly due to higher voltage and fill factor. The coverage, pore-filling, and morphology of the deposited perovskite are found to be critical in photovoltaic performance of the mesoporous TiO2 based perovskite solar cells. (C) 2014 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.
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页数:8
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共 24 条
[21]   Reproducible Fabrication of Efficient Perovskite-based Solar Cells: X-ray Crystallographic Studies on the Formation of CH3NH3PbI3 Layers [J].
Wakamiya, Atsushi ;
Endo, Masaru ;
Sasamori, Takahiro ;
Tokitoh, Norihiro ;
Ogomi, Yuhei ;
Hayase, Shuzi ;
Murata, Yasujiro .
CHEMISTRY LETTERS, 2014, 43 (05) :711-713
[22]   Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements [J].
Zaban, A ;
Greenshtein, M ;
Bisquert, J .
CHEMPHYSCHEM, 2003, 4 (08) :859-864
[23]   Solid-State Mesostructured Perovskite CH3NH3PbI3 Solar Cells: Charge Transport, Recombination, and Diffusion Length [J].
Zhao, Yixin ;
Nardes, Alexandre M. ;
Zhu, Kai .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (03) :490-494
[24]   Impact of High Charge-Collection Efficiencies and Dark Energy-Loss Processes on Transport, Recombination, and Photovoltaic Properties of Dye-Sensitized Solar Cells [J].
Zhu, Kai ;
Jang, Song-Rim ;
Frank, Arthur J. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (09) :1070-1076