Small boron carbon chains stabilized in rare earth metallic frameworks: A bonding analysis

被引：25

作者：

Bauer, J ^{[1
]}

Boucekkine, G ^{[1
]}

Frapper, G ^{[1
]}

Halet, JF ^{[1
]}

Saillard, JY ^{[1
]}

Zouchoune, B ^{[1
]}

机构：

[1] UNIV RENNES 1,UMR CNRS 6511,CHIM SOLIDE & INORGAN MOL LAB,F-35042 RENNES,FRANCE

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1997年 / 133卷 / 01期

关键词：

D O I：

10.1006/jssc.1997.7425

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bonding properties of rare earth metal boron carbide compounds are analyzed by means of extended Huckel tight-binding and ab initio calculations. Results indicate that these compounds san he described in first approximation as being built of cumulene-like BxCy anionic units interacting with not fully oxidized metallic cations. (C) 1997 Academic Press.

引用

页码：190 / 194

页数：5

共 28 条

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