Preparation, structure and discrimination of a chiral bimolecular crystal by the self-assembly of 3-indolepropionic acid and phenanthridine

被引:46
作者
Koshima, H
Hayashi, E
Matsuura, T
Tanaka, K
Toda, F
Kato, M
Kiguchi, M
机构
[1] EHIME UNIV,FAC ENGN,DEPT APPL CHEM,MATSUYAMA,EHIME 790,JAPAN
[2] HITACHI LTD,ADV RES LAB,HATOYAMA,SAITAMA 35003,JAPAN
关键词
D O I
10.1016/S0040-4039(97)01072-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Although 3-indolepropionic acid and phenanthridine are achiral molecules, a chiral bimolecular crystal is spontaneously formed; torsional conformation of the propionic acid group plays an important role in the helix formation through hydrogen bonding chain within the crystal lattice. (C) 1997 Elsevier Science Ltd.
引用
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页码:5009 / 5012
页数:4
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