Aminosilylation of aldehydes mediated by lithium perchlorate:: novel method for synthesis of α-silylamines

被引:29
作者
Naimi-Jamal, MR
Mojtahedi, MM
Ipaktschi, J
Saidi, MR
机构
[1] Sharif Univ Technol, Dept Chem, Tehran, Iran
[2] Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 24期
关键词
D O I
10.1039/a904498a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
alpha-Silylated N,N-dialkylamines 7a-k were easily synthesized in good to excellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phenyldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilyllithium 6, in concentrated ethereal lithium perchlorate solution.
引用
收藏
页码:3709 / 3711
页数:3
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