Improved synthesis of perfluorooctylpropyl amine

被引：7

作者：

Abulikemu, A

Halász, G

Csámpai, A

Gömöry, A

Rábai, J

机构：

[1] Eotvos Lorand Univ, Dept Organ Chem, H-1518 Budapest 112, Hungary

[2] Eotvos Lorand Univ, Dept Gen & Inorgan Chem, H-1518 Budapest 112, Hungary

[3] Hungarian Acad Sci, Inst Chem, Chem Res Ctr, H-1525 Budapest 112, Hungary

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 07期

基金：

匈牙利科学研究基金会;

关键词：

perfluorooctylpropyl amine; preparation; dehalogenation;

D O I：

10.1016/j.jfluchem.2004.02.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrazinolysis of N-perfluorooctylpropyl phthalimide is an easy route to scale up for the title compound. Both the alkylation of potassium phthalimide with perfluorooctylpropyl iodide and the hydrogenolysis of the adduct of perfluoroctyl iodide to N-allyl-phthalimide provide this amine precursor in good yields. The latter procedure, however, has a better atom economy, since it requires only three steps from perfluorooctyl iodide. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1143 / 1146

页数：4

共 11 条

[1] Synthesis of amino terminated semifluorinated long-chain alkanethiols [J].