Aluminosilicate nanohybrid materials. Intercalation of polystyrene in kaolinite

被引：74

作者：

Elbokl, Tamer A.

Detellier, Christian ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Univ Ottawa, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2006年 / 67卷 / 5-6期

基金：

加拿大自然科学与工程研究理事会;

关键词：

nanostructures; polymers; infrared spectroscopy; thermogravimetric analysis (TGA); X-ray diffraction;

D O I：

10.1016/j.jpcs.2006.01.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports on the intercalation of polystyrene into the interlamellar spaces of kaolinite. The intercalation was achieved by a free radical polymerization reaction of styrene in the presence of a kaolinite-DMSO intercalate as a starting material. The results of the XRD, FTIR and TGA analyses confirmed the intercalation of polystyrene in the interlamellar spaces of kaolinite. C-13 CP/MAS and DD/MAS spectra indicated the almost complete displacement of DMSO by polystyrene chains and the rigidity of the latter in the interlamellar spaces. Si-29 and Al-27 NMR spectra of the starting materials and the products are also discussed. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：950 / 955

页数：6

共 56 条

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