Diastereoselective oxidative addition of allyl chloride to planar-chiral cyclopentadienyl-ruthenium complexes

被引：25

作者：

Matsushima, Y ^{[1
]}

Onitsuka, K ^{[1
]}

Takahashi, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 16期

关键词：

D O I：

10.1021/om049616d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with allyl chloride at room temperature resulted in the diastereoselective formation of pi-allyl-ruthenium complexes, in which the chirality at the Ru center depended on the substituent at the 4-position of the cyclopentadienyl group. Epimerization at the Ru center of pi-allyl complexes at 90 degreesC suggested that the diastereoselectivity was under kinetic control.

引用

页码：3763 / 3765

页数：3

共 39 条

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