Synthesis, Structure, and Application of Self-Assembled Copper(II) Aqua Complex by H-Bonding for Acceleration of the Nitroaldol Reaction on Water

被引：47

作者：

Jammi, Suribabu ^{[1
]}

Ali, Md Ashif ^{[1
]}

Sakthivel, Sekarpandi ^{[1
]}

Rout, Laxmidhar ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 02期

关键词：

C-C coupling; heterogeneous catalysis; hydrogen bonds; nitroaldol reaction; self-assembly; ASYMMETRIC HENRY REACTION; CONJUGATED NITROALKENES; AQUEOUS-MEDIA; EFFICIENT SYNTHESIS; ORGANIC-COMPOUNDS; ALDOL REACTION; CATALYSIS; CHLORIDE; AMINOALCOHOLS; ADDITIVES;

D O I：

10.1002/asia.200800339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) aqua complex 1 has been prepared in a one-pot synthesis. The single crystal X-ray analysis showed that the complex is self-assembled through aqua ligands by H-bond interactions and the copper(II) atoms are pentacoordinated with square pyramidal geometry. Complex 1 has been studied for the acceleration of the nitroalodol reaction on water. It is a clean technological process and the catalyst can be recycled without loss of activity.

引用

页码：314 / 320

页数：7

共 69 条

[61] X-ray crystallographic analyses of complexes between bovine β-trypsin and Schiff base copper(II) or iron(III) chelates [J].

Toyota, E ;

Ng, KKS ;

Sekizaki, H ;

Itoh, K ;

Tanizawa, K ;

James, MNG .

JOURNAL OF MOLECULAR BIOLOGY, 2001, 305 (03) :471-479

[62]

Trost B.M., 2002, Angew. Chem, V114, P869

[63]

Trost BM, 2002, ANGEW CHEM INT EDIT, V41, P841, DOI 10.1002/1521-3773(20020301)41:5<841::AID-ANIE841>3.0.CO

[64]

2-2

[65] 'Green' synthesis of nitro alcohols catalyzed by solid-supported tributylammonium chloride in aqueous medium [J].

Wang, ZT ;

Xue, HQ ;

Wang, SC ;

Yuan, CG .

CHEMISTRY & BIODIVERSITY, 2005, 2 (09) :1195-1199

[66] NITRO-COMPOUNDS .3. SYNTHESIS OF D-2-AMINO-2-DEOXYARABINOSE AND L-2-AMINO-2-DEOXYARABINOSE AND 1,4-DIDEOXY-1,4-IMINOLYXITOL BY (C2+C3)-NITROALDOL ADDITION WITH 2-O-BENZYLGLYCERALDEHYDE [J].

WEHNER, V ;

JAGER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (10) :1169-1171

[67]

Wolfe J.P., 2007, NAME REACTIONS FUNCT, P645

[68] A new copper(I)-tetrahydrosalen-catalyzed asymmetric Henry reaction and its extension to the synthesis of (S)-norphenylephrine [J].

Xiong, Yan ;

Wang, Fei ;

Huang, Xiao ;

Wen, Yuehong ;

Feng, Xiaoming .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (03) :829-833

[69] Organocatalytic biomimetic reduction of conjugated nitroalkenes [J].

Zhang, Zhiguo ;

Schreiner, Peter R. .

SYNTHESIS-STUTTGART, 2007, (16) :2559-2564

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