Total photoabsorption cross-sections of CF3SF5 in the C, F and SK-shell regions

被引：13

作者：

Ibuki, T

Shimada, Y

Nagaoka, S

Fujii, A

Hino, M

Kakiuchi, T

Okada, K

Tabayashi, K

Matsudo, T

Yamana, Y

Suzuki, IH

Tamenori, Y

机构：

[1] Kyoto Univ, Fushimi Ku, Kyoto 6128522, Japan

[2] Ehime Univ, Dept Fundamental Mat Sci, Matsuyama, Ehime 7908577, Japan

[3] Hiroshima Univ, Dept Chem, Higashihiroshima 7398526, Japan

[4] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan

[5] SPring 8, Japan Synchrotron Radiat Res Inst, Mikazuki, Hyogo 6795198, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 392卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.04.118

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Total photoabsorption cross-sections of trifluoromethyl sulfur pentafluoride, CF3SF5, were measured in the C, F and S K-shell regions by using a double ionization chamber and synchrotron radiation at the SPring-8 facility. The maximum cross sections were found to be 6.3, 5.0 and 1.1 Mb for the C, F and S K-edges, respectively. The spectral features in the F K-shell region were characterized by the photoabsorption spectra of CF4 and SF6 and those in the S K-shell region resemble the peaks of SF6. The observed peaks for CF3SF5 were tentatively assigned on the basis of a comparison with those for CF4 and SF6 measured simultaneously for references. (C) 2004 Elsevier B.V. All rights reserved.

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页码：303 / 308

页数：6

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