The Coupling of Tertiary Amines with Acrylate Derivatives via Visible-Light Photoredox Catalysis

被引：84

作者：

Dai, Xiaojun ^{[1
]}

Cheng, Dongping ^{[2
]}

Guan, Baochuan ^{[1
]}

Mao, Wenjuan ^{[1
]}

Xu, Xiaoliang ^{[1
]}

Li, Xiaonian ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Inst Ind Catalysis, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 15期

关键词：

ALPHA-AMINOALKYL RADICALS; C-H FUNCTIONALIZATION; DUAL CATALYSIS; AEROBIC OXIDATION; PHOTOCATALYSIS; ALKENES; BONDS; PHOTOOXIDATION; EFFICIENT; ARYLATION;

D O I：

10.1021/jo501097b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalyzed by Ru(bpy)(3)(BF4)(2), the photoredox coupling of tertiary amines with acrylate derivatives including Baylis-Hillman adducts under visible light irradiation was successfully established. The scope of the substrates was broad, and thus an array of gamma-aminobutyric ester derivatives was obtained in moderate to good yields.

引用

页码：7212 / 7219

页数：8

共 86 条

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