New diterpene glycosides of the fungus Acremonium striatisporum isolated from a sea cucumber

被引：23

作者：

Afiyatullov, Shamil Sh. ^{[1
]}

Kalinovsky, Anatoly I. ^{[1
]}

Pivkin, Mikhail V. ^{[1
]}

Dmitrenok, Pavel S. ^{[1
]}

Kuznetsova, Tatyana A. ^{[1
]}

机构：

[1] Russian Acad Sci, Far E Branch, Pacific Inst Bioorgan Chem, Vladivostok 22, Russia

来源：

NATURAL PRODUCT RESEARCH | 2006年 / 20卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

Acremonium striatisporum; diterpene glycosides; marine fungi;

D O I：

10.1080/14786410500277720

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three new diterpene glycosides, virescenosides V ( 1), W ( 2), and X ( 3) have been isolated from a marine strain of Acremonium striatisporum KMM 4401 associated with the holothurian Eupentacta fraudatrix. Their structures have been elucidated on the basis of high resolution mass spectrometry, 1D and 2D NMR (H-1, C-13, DEPT, COSY 45, COSY RCT, HSQC, HMBC, and NOESY spectra) as 19-O-beta-D-altropyranosyl-7-oxo-isopimara-8( 14), 15-diene-2 alpha, 3 beta-diol ( 1), 19-O-beta-D-altropyranosyl-isopimara-7,15-diene-2 alpha, 3 beta, 6 alpha-triol ( 2), and 19-O-beta-D- altropyranosyl- isopimara-8,15-diene-2 alpha, 3 beta, 7 alpha-triol ( 3).

引用

页码：902 / 908

页数：7

共 8 条

[1] New glycosides of the fungus Acremonium striatisporum isolated from a sea cucumber [J].

Afiyatullov, SS ;

Kalinovsky, AI ;

Kuznetsova, TA ;

Pivkin, MV ;

Prokof'eva, NG ;

Dmitrenok, PS ;

Elyakov, GB .

JOURNAL OF NATURAL PRODUCTS, 2004, 67 (06) :1047-1051

[2] New diterpene glycosides of the fungus Acremonium striatisporum isolated from a sea cucumber [J].

Afiyatullov, SS ;

Kalinovsky, AI ;

Kuznetsova, TA ;

Isakov, VV ;

Pivkin, MV ;

Dmitrenok, PS ;

Elyakov, GB .

JOURNAL OF NATURAL PRODUCTS, 2002, 65 (05) :641-644

[3] New diterpenic altrosides of the fungus Acremonium striatisporum isolated from a sea cucumber [J].

Afiyatullov, SS ;

Kuznetsova, TA ;

Isakov, VV ;

Pivkin, MV ;

Prokof'eva, NG ;

Elyakov, GB .

JOURNAL OF NATURAL PRODUCTS, 2000, 63 (06) :848-850

[4]

DEKIMPE N, 1982, J ORG CHEM, V47, P3628

[5] ASSIGNMENT OF ABSOLUTE-CONFIGURATION OF SUGARS BY GIC OF THEIR ACETYLATED GLYCOSIDES FORMED FROM CHIRAL ALCOHOLS [J].

LEONTEIN, K ;

LINDBERG, B ;

LONNGREN, J .

CARBOHYDRATE RESEARCH, 1978, 62 (02) :359-362

[6] C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF NATURALLY OCCURRING SUBSTANCES .11. BIOSYNTHESIS OF VIRESCENOSIDES [J].

POLONSKY, J ;

BUCKWALTER, BL ;

CECCHERELLI, P ;

CAGNOLIB.N ;

BASKEVITCH, Z ;

WENKERT, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) :4369-+

[7]

SANFELICIANO A, 1988, PHYTOCHEMISTRY, V27, P2241, DOI 10.1016/0031-9422(88)80134-1

[8] C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF NATURALLY OCCURRING SUBSTANCES .10. PIMARADIENES [J].

WENKERT, E ;

BUCKWALTER, BL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) :4367-+

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