Comparison of zinc and cadmium coordination environments in synthetic analogues of carbonic anhydrase: Synthesis and structure of {[Pim(Pri,But)]Cd(OH2)(OClO3)}(ClO4)

被引：41

作者：

Kimblin, C ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 24期

关键词：

D O I：

10.1021/ic961007d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cadmium complex {[Pim(Pri,But)]Cd(OH2)(OCLO(3))}-(ClO4), synthesized by the reaction of Cd(ClO4)(2) . 6H(2)O with Pim(Pri,But), has been structurally-characterized by X-ray diffraction; comparison with its zinc counterpart {[Pim(Pri,But)]ZnOH}(ClO4) reveals structural and chemical differences between the metals in environments that are closely related to the active site of carbonic anhydrase.

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页码：6912 / &

页数：3

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