A Highly Connected Porous Coordination Polymer with Unusual Channel Structure and Sorption Properties

被引：382

作者：

Zhang, Yue-Biao ^{[1
]}

Zhang, Wei-Xiong ^{[1
]}

Feng, Fei-Yue ^{[1
]}

Zhang, Jie-Peng ^{[1
]}

Chen, Xiao-Ming ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 29期

关键词：

cage compounds; coordination polymers; crystal engineering; metal-organic frameworks; porous materials; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; BUILDING-BLOCKS; DESIGN; CHEMISTRY; PORES; NET;

D O I：

10.1002/anie.200901964

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making connections: A hydroxy-centered trinuclear nickel cluster has been employed to construct a highly connected, highly symmetric framework with a uninodal nine-connected topology. An array of triakis tetrahedra leads to a biporous intersecting-channel system (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5287 / 5290

页数：4

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