Chiral salen manganese complex encapsulated within zeolite Y: A heterogeneous enantioselective catalyst for the epoxidation of alkenes

被引:245
作者
Sabater, MJ [1 ]
Corma, A [1 ]
Domenech, A [1 ]
Fornes, V [1 ]
Garcia, H [1 ]
机构
[1] UNIV POLITECN VALENCIA, CSIC, INST TECNOL QUIM, VALENCIA 46071, SPAIN
关键词
D O I
10.1039/a701337j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chiral (salen)Mn-III complex [salen: trans-(R,R)-1,2-bis(salicylideneamino)cyclohexane] analogous to Jacobsen's catalyst is prepared inside the supercages of zeolite Y, showing catalytic activity very similar to that of the chloride complex in the homogeneous phase.
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页码:1285 / 1286
页数:2
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