The asymmetric cyclohexenylation of 2,2-dimethyl-2,3-dihydrofuran

被引：29

作者：

Hennessy, AJ ^{[1
]}

Malone, YM ^{[1
]}

Guiry, PJ ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)00143-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium catalysed asymmetric cyclohexenylation of 2,2-dimethyl-2,3-dihydrofuran is described. Use of this substrate allowed for an easy and direct comparison of a range of ligands in this reaction. The ligands employed included BINAP and phosphinamines and enantioselectivities of up to 97% were obtained with tert-leucinol-derived diphenylphosphinoaryloxazolines. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2261 / 2264

页数：4

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