Enantioselective total synthesis of both diastereomers of preclavulone-A methyl ester

被引：14

作者：

Ito, Hisanaka ^{[1
]}

Momose, Tsutomu ^{[1
]}

Konishi, Masami ^{[1
]}

Yamada, Eriko ^{[1
]}

Watanabe, Kinzo ^{[1
]}

Iguchi, Kazuo ^{[1
]}

机构：

[1] Tokyo Univ Pharm & Life Sci, Sch Life Sci, Hachioji, Tokyo 1920392, Japan

来源：

TETRAHEDRON | 2006年 / 62卷 / 44期

关键词：

D O I：

10.1016/j.tet.2006.08.068

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantioselective total synthesis of preclavulone-A methyl ester and its diastereomer was achieved from enantiomerically pure 5 in a stereocontrolled manner. The absolute stereochemistry of naturally occurring preclavulone-A methyl esters was determined by comparison of the [alpha](D) value. (c) 2006 Published by Elsevier Ltd.

引用

页码：10425 / 10433

页数：9

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