Lithium and sodium fullerides prepared in liquid ammonia

被引:10
作者
Fullagar, WK
Reynolds, PA
White, JW
机构
[1] Research School of Chemistry, Australian National University, Canberra
关键词
fullerenes; chemical synthesis; X-ray scattering; synchrotron radiation;
D O I
10.1016/S0038-1098(97)00229-9
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Lithium and sodium fullerides are the least well characterized of the alkali fullerides. We report the liquid ammonia synthesis and structural characterization of Na2C60(NH3)(8), which contains a rhombohedral C-60 stacking not previously reported in simple fullerides. We also describe A(x)C(60) (A = Li Or Na, x = 2 and 3) samples prepared by the desorption of ammonia from corresponding ammoniated fullerides. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:23 / 27
页数:5
相关论文
共 21 条
[1]   MOLECULAR-STRUCTURE OF THE FULLERIDE ANIONS IN SUPERCONDUCTING K3C60 AND INSULATING K6C60 DETERMINED BY POWDER NEUTRON-DIFFRACTION [J].
ALLEN, KM ;
DAVID, WIF ;
FOX, JM ;
IBBERSON, RM ;
ROSSEINSKY, MJ .
CHEMISTRY OF MATERIALS, 1995, 7 (04) :764-770
[2]   THE KINETICS OF THE REACTION OF C-60 AND C-70 FULLERENES WITH SODIUM METAL IN TOLUENE SOLUTION [J].
BEZMELNITSYN, VN ;
DITYATEV, AA ;
DAVYDOV, VY ;
SHEPETOV, NG ;
ELETSKII, AV ;
SINYANSKII, VF .
CHEMICAL PHYSICS LETTERS, 1995, 237 (3-4) :246-249
[3]   INELASTIC NEUTRON-SCATTERING AND SUPERCONDUCTIVITY OF RB3C60(NH3)(X) [J].
CARLILE, CJ ;
DURAND, R ;
FULLAGAR, WK ;
REYNOLDS, PA ;
TROUW, F ;
WHITE, JW .
MOLECULAR PHYSICS, 1995, 86 (01) :19-37
[4]   Rapid synthesis of alkali-metal fullerides using a microwave-induced argon plasma [J].
Douthwaite, RE ;
Green, MLH ;
Rosseinsky, MJ .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :394-400
[5]   X-RAY AND NEUTRON POWDER DIFFRACTION FROM RB3C60(NH3)(X) AND LI3C60(NH3)(X) [J].
DURAND, R ;
FULLAGAR, WK ;
LINDSELL, G ;
REYNOLDS, PA ;
WHITE, JW .
MOLECULAR PHYSICS, 1995, 86 (01) :1-17
[6]   REVERSIBLE ALKALI-METAL REDUCTION OF C-60 IN LIQUID-AMMONIA - 1ST OBSERVATION OF NEAR-INFRARED SPECTRUM OF C-60(5-) [J].
FULLAGAR, WK ;
GENTLE, IR ;
HEATH, GA ;
WHITE, JW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (06) :525-527
[7]   DISPROPORTIONATION OF RB3C60 BY AMMONIA TO PRODUCE 2 NEW AMMONIATED FULLERIDES [J].
FULLAGAR, WK ;
COOKSON, D ;
RICHARDSON, JW ;
REYNOLDS, PA ;
WHITE, JW .
CHEMICAL PHYSICS LETTERS, 1995, 245 (01) :102-106
[8]   (NH3)(6)NA3C60 - ROOM-TEMPERATURE SYNTHESIS OF A BODY-CENTERED-CUBIC C-60(3-) COMPOUND [J].
HENRY, PF ;
ROSSEINSKY, MJ ;
WATT, CJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (20) :2131-2132
[9]   ORIENTATIONAL DISORDER OF C-60 IN LI2CSC60 [J].
HIROSAWA, I ;
PRASSIDES, K ;
MIZUKI, J ;
TANIGAKI, K ;
GEVAERT, M ;
LAPPAS, A ;
COCKCROFT, JK .
SCIENCE, 1994, 264 (5163) :1294-1297
[10]  
Larson AC, 1985, GEN STRUCTURE ANAL S