REVERSIBLE ALKALI-METAL REDUCTION OF C-60 IN LIQUID-AMMONIA - 1ST OBSERVATION OF NEAR-INFRARED SPECTRUM OF C-60(5-)

被引：42

作者：

FULLAGAR, WK

GENTLE, IR

HEATH, GA

WHITE, JW

机构：

[1] AUSTRALIAN NATL UNIV,THE FACULTIES,CHEM RES SCH,GPO BOX 4,CANBERRA,ACT 2601,AUSTRALIA

[2] AUSTRALIAN NATL UNIV,THE FACULTIES,DEPT CHEM,CANBERRA,ACT 2601,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 06期

关键词：

D O I：

10.1039/c39930000525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new method for the homogeneous redox manipulation of alkali-metal fullerides with a solution of rubidium in liquid ammonia at -40-degrees-C has been used to prepare the C-60(2-), C-60(3-), C-60(4-) and C-60(-) ions, the near IR spectra being recorded at various stages of the titration; the excitation energy of the main band in C-60(5-) (10 500 cm-1) is close to that of C-60(1-) and the principal band in the C-60(2-) spectrum.

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页码：525 / 527

页数：3

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