Nanoporous, hypercrosslinked polypyrroles: effect of crosslinking moiety on pore size and selective gas adsorption

被引：84

作者：

Germain, Jonathan ^{[2
]}

Frechet, Jean M. J. ^{[1
,2
]}

Svec, Frantisek ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Coll Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 12期

关键词：

HIGH-SURFACE-AREA; POROUS POLYMER MONOLITHS; HYDROGEN STORAGE; CONDUCTING POLYMER; STATIONARY PHASES; NETWORKS; CARBON; POLYANILINE; CHROMATOGRAPHY; POLYSTYRENE;

D O I：

10.1039/b821233c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous, hypercrosslinked polypyrroles with surface areas of up to 720 m(2) g(-1) have been prepared; their pore sizes and gas adsorption selectivities were controlled by varying the size of the crosslinking units.

引用

页码：1526 / 1528

页数：3

共 31 条

[1] Polyaniline-deposited porous carbon electrode for supercapacitor [J].

Chen, WC ;

Wen, TC ;

Teng, HS .

ELECTROCHIMICA ACTA, 2003, 48 (06) :641-649

[2]

CHO SJ, 2002, PREPR PAP AM CHEM SO, P47

[3] HIGH CHARGE-DENSITY CONDUCTING POLYMER GRAPHITE FIBER-COMPOSITE ELECTRODES FOR BATTERY APPLICATIONS [J].

COFFEY, B ;

MADSEN, PV ;

POEHLER, TO ;

SEARSON, PC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (02) :321-325

[4] Electropolymerization of polyaniline on high surface area carbon substrates [J].

Dalmolin, C ;

Canobre, SC ;

Biaggio, SR ;

Rocha-Filho, RC ;

Bocchi, N .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 578 (01) :9-15

[5] STRUCTURE AND PROPERTIES OF HYPERCROSSLINKED POLYSTYRENE - THE 1ST REPRESENTATIVE OF A NEW CLASS OF POLYMER NETWORKS [J].

DAVANKOV, VA ;

TSYURUPA, MP .

REACTIVE POLYMERS, 1990, 13 (1-2) :27-42

[6] Synthesis of a boron-containing conducting polymer from the anodic oxidation of Tris(pyrrolyl)borane [J].

Douglade, G ;

Fabre, B .

SYNTHETIC METALS, 2002, 129 (03) :309-314

[7]

Germain J., 2007, PMSE PREPR, V97, P272

[8]

GERMAIN J, 2008, CHEM MATER, P2034

[9] Hypercrosslinked polyanilines with nanoporous structure and high surface area:: potential adsorbents for hydrogen storage [J].

Germain, Jonathan ;

Frechet, Jean M. J. ;

Svec, Frantisek .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (47) :4989-4997

[10] High surface area nanoporous polymers for reversible hydrogen storage [J].

Germain, Jonathan ;

Hradil, Jiri ;

Frechet, Jean M. J. ;

Svec, Frantisek .

CHEMISTRY OF MATERIALS, 2006, 18 (18) :4430-4435

← 1 2 3 4 →