Solid-state IR-LD spectroscopy of codeine and N-norcodeine derivatives

被引:21
作者
Bakalska, Rumyana [1 ]
Ivanova, Bojidarka
Kolev, Tsonko
机构
[1] Paisij Hilendarski Univ Plovdiv, Dept Organ Chem, BG-4000 Plovdiv, Bulgaria
[2] Sofia Univ St Kl Ohridki, Fac Chem, Dept Analyt Chem, Sofia 1164, Bulgaria
[3] Bulgarian Acad Sci, Inst Organ Chem, BU-1113 Sofia, Bulgaria
来源
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2006年 / 4卷 / 03期
关键词
3-ethoxy-4-(N-norcodeino-)-cyclobutene-1,2-dione; codeine dihydrogenphosphate; IR-LD spectroscopy;
D O I
10.2478/s11532-006-0018-0
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Linear-dichroic infrared spectra (IR-LD) of 3-ethoxy-4-(N-norcodeino-)cyclobutene-1,2-dione (1) and codeine dihydrogenphosphate (Codeinum phosphoricum) (2), oriented as solid suspensions in nematic liquid crystals, have been measured. IR characteristic band assignments were made, and used in stereo-structural predictions. The results were compared with crystallographic structures of similar organic systems, and found to be in good agreement. (C) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.
引用
收藏
页码:533 / 542
页数:10
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