Syntheses and structures of iron(III) complexes of simple N-donor ligands

被引：56

作者：

Cotton, SA ^{[1
]}

Franckevicius, V

Fawcett, J

机构：

[1] Uppingham Sch, Uppingham LE15 9QE, Rutland, England

[2] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

POLYHEDRON | 2002年 / 21卷 / 20期

关键词：

iron(III); single-crystal X-ray; N-donor; terpyridyl;

D O I：

10.1016/S0277-5387(02)01137-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：2055 / 2061

页数：7

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