TRICHLORO(1,4,7-TRITHIACYCLONONANE-S,S',S'')IRON(III), [FECL3(C6H12S3)]

被引：7

作者：

BALLESTER, J

PARKER, OJ

BRENEMAN, GL

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193012247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of red trichloro(1,4,7-trithiacyclononane-S,S',S'')iron(III), [FeCl3(C6H12S3)], containing a distorted octahedral high-spin [Fe(III)Cl3S3] core, is reported. The structure of [FeCl3(C6H12S3)] consists of discrete molecules containing six-coordinate Fe atoms. The three chlorides range in distance from the Fe atom from 2.252 (2) to 2.276 (2) angstrom forming the three legs of a table with the C6H12S3 ring forming the table top. The three S atoms in the puckered ring coordinate to the Fe atom at distances ranging from 2.538 (3) to 2.585 (3) angstrom.

引用

页码：712 / 714

页数：3

共 13 条

[1] (1,4,7-TRIS(4-TERT-BUTYL-2-MERCAPTOBENZYL)-1,4,7-TRIAZACYCLONONANE)IRON(III) - A MODEL FOR THE IRON SULFUR CENTER IN NITRILE HYDRATASE FROM BREVIBACTERIUM, SP [J].