Synthesis of fagopyritols A1 and B1 from D-chiro-inositol

被引：23

作者：

Cid, MB ^{[1
]}

Alfonso, F ^{[1
]}

Martín-Lomas, M ^{[1
]}

机构：

[1] CSIC, Grp Carbohidratos, Inst Invest Quim, Seville 41092, Spain

来源：

CARBOHYDRATE RESEARCH | 2004年 / 339卷 / 13期

关键词：

regioselective glycosylation; glycosyl inositols; insulin mimetics;

D O I：

10.1016/j.carres.2004.06.021

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

Fagopyritol Al (3-O-alpha-D-galactopyranosyl-D-chiro-inositol) and fagopyritol B1 (2-O-alpha-D-galactopyranosyl-D-chiro-inositol) have been synthesized by glycosylation of the diequatorial diol 1,4,5,6-tetra-O-benzoyl-D-chiro-inositol, readily obtained from D-chiro-inositol, with 2,3,4,6-tetra-O-benzyl-D-galactopyranosyl trichloroacetimidate. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2303 / 2307

页数：5

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2-Q

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