A highly efficient synthesis of triisopropylsilyldifluorobromopropyne yields a versatile gem-difluoromethylene building block

被引:26
作者
Wang, ZG [1 ]
Hammond, GB [1 ]
机构
[1] Univ Massachusetts, Dept Chem & Biochem, N Dartmouth, MA 02747 USA
关键词
D O I
10.1039/a907784g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Triisopropylsilyldifluorobromopropyne, readily prepared in excellent yield from the reaction of lithium triisopropylsilylacetylide with CF2Br2, provides a convenient entry into a functionalized CF2 synthon.
引用
收藏
页码:2545 / 2546
页数:2
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