Two novel three-dimensional Nd-adipates: influence of hydrothermal reaction temperature on framework topology

被引：30

作者：

Borkowski, LA

Cahill, CL

机构：

[1] George Washington Univ, Dept Chem, Washington, DC 20052 USA

[2] Carnegie Inst Washington, Geophys Lab, Washington, DC 20015 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 06期

关键词：

metal-organic framework; hydrothermal; crystal structure;

D O I：

10.1016/j.inoche.2004.04.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel three dimensional neodymium adipates have been synthesized through hydrothermal techniques. Both GWMOF-1 (C6H8O4)(3)Nd-2(H2O2) and GWMOF-2 ((C6H8O4)(3)Nd-2(H2O) . H2O) are constructed of chains of edge-shared NdO8(H2O) polyhedra that are cross-linked by adipic acid molecules to form framework structures. The structures differ in the conformations of the acid chains and the resulting framework topologies. Both materials are thermally stable to approximately 370 degreesC. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：725 / 728

页数：4

共 15 条

[1] [Anonymous], 2002, JADE V 6 1
[2] *BRUK AXS INC, 1998, SAINTPLUS V 6 01
[3] *BRUK AXS INC, 1998, SMART V 5 053
[4] Microporous rare earth coordination polymers: Effect of lanthanide contraction on crystal architecture and porosity
Dimos, A
Tsaousis, D
Michaelides, A
Skoulika, S
Golhen, S
Ouahab, L
Didierjean, C
Aubry, A
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (06) : 2616 - 2622
[5] A novel three-dimensional open framework constructed from infinite chain's of edge-sharing CeO8(H2O) polyhedron:: [Ce2(ad)3(H2O)2]n
Duan, LM
Xu, JQ
Xie, FT
Liu, YB
Ding, H
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (02) : 216 - 219
[6] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry
Férey, G
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (10) : 3084 - 3098
[7] The role of temperature in the synthesis of hybrid inorganic-organic materials:: the example of cobalt succinates
Forster, PM
Burbank, AR
Livage, C
Férey, G
Cheetham, AK
[J]. CHEMICAL COMMUNICATIONS, 2004, (04) : 368 - 369
[8] Crystal structure and spectroscopic study of novel two- and three-dimensional photoluminescent Eu(III)-adipate compounds
Kim, Y
Suh, M
Jung, DY
[J]. INORGANIC CHEMISTRY, 2004, 43 (01) : 245 - 250
[9] Assembly of a porous three-dimensional coordination polymer:: Crystal structure of {[La2(adipate)3(H2O)4]6H2O}n
Kiritsis, V
Michaelides, A
Skoulika, S
Golhen, S
Ouahab, L
[J]. INORGANIC CHEMISTRY, 1998, 37 (13) : 3407 - +
[10] Luminescent lanthanide coordination polymers
Ma, L
Evans, OR
Fowman, BM
Lin, WB
[J]. INORGANIC CHEMISTRY, 1999, 38 (25) : 5837 - 5840

← 1 2 →