Stereoselective synthesis of (-)-metasequoic acid B

被引：18

作者：

Abad, A

Agullo, C

Arno, M

Cantin, A

Cunat, AC

Meseguer, B

Zaragoza, RJ

机构：

[1] Departamento de Química Orgánica, Facultad de Químicas, Universidad de Valencia, 46100-Burjassot, Valencia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 12期

关键词：

D O I：

10.1039/a700354d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective synthesis of the ent-labdane diterpene(-)-metasequoic acid B (ent-2) and its corresponding methyl ester (ent-3) starting from (R)-(-)-carvone 6 is described. The synthesis is based on the construction of a phenanthrenone system 5 which is converted into the ent-labdane skeleton after selective cleavage of the C(13)-C(14) bond.

引用

页码：1837 / 1843

页数：7

共 24 条

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