Facile synthetic route of polycarbosilane as a SiC precursor with zeolite catalysts

被引：12

作者：

Nguyen, Chi Thanh

Hong, Lan-Young

Kim, Dong-Pyo ^{[1
]}

Lee, Jin-Yong

Woo, Hee-Gweon

机构：

[1] Chungnam Natl Univ, Dept Fine Chem Eng & Chem, Taejon 305764, South Korea

[2] Agcy Def Dev, Taejon 305764, South Korea

[3] Chonnam Natl Univ, Dept Chem, Coll Nat Sci, Kwangju 500757, South Korea

来源：

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2006年 / 114卷 / 1330期

关键词：

polycarbosilane; zeolite Y; solid acid catalyst; commercial polycarbosilane;

D O I：

10.2109/jcersj.114.487

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Polycarbosilane (PCS), a well known preceramic polymer which is frequently used as an SiC precursor, was synthesized from the thermal decomposition of polydimethylsilane (PDMS) in the presence of various types of zeolites as catalysts. The PDMS with different types and amounts of the zeolite catalysts was heated at 350 degrees C for 6 h, followed by heating at 400 degrees C for an additional 6 h in an autoclave. The use of the zeolite catalysts allowed the PCS to be synthesized under milder conditions and with a higher efficiency than those observed in the Yajima process, by accelerating the thermal decomposition of the PDMS. The PCS product was separated into three fractions, viz. the insoluble fraction, the solid and soluble fraction, and the low molecular weight liquid product. The solid and soluble PCS was characterized by TGA, FT-IR, GPC and NMR analysis, in order to study the effect of the catalysts on the chemical properties of the polymer.

引用

页码：487 / 491

页数：5