Crown ethers derived from cyclohexane. Influence of their stereochemistry in complexation and transport

被引：16

作者：

Costero, AM ^{[1
]}

Villarroya, JP ^{[1
]}

Gil, S ^{[1
]}

Aurell, MJ ^{[1
]}

de Arellano, MCR ^{[1
]}

机构：

[1] Univ Valencia, Dept Quim Organ, E-46100 Burjassot, Spain

来源：

TETRAHEDRON | 2002年 / 58卷 / 33期

关键词：

complexation; cyclohexyl-crown ethers; conformational regulation;

D O I：

10.1016/S0040-4020(02)00681-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Crown ethers derived from cyclohexane have been prepared. The trans stereochemistry of the substituents on the carbocyclic ring makes that only one conformation can complex cations. The influence of the stereochemistry in complexation has been studied. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6729 / 6734

页数：6

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