Infrared spectroscopy of bare single crystal and nano-particle covered surfaces

被引：1

作者：

Marinkovic, Nebojsa S.

Adzic, Radoslav R.

机构：

[1] Brookhaven Natl Lab, Ctr Catalyt Res, Upton, NY 11973 USA

[2] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA

[3] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2006年 / 71卷 / 8-9期

关键词：

infrared; spectroelectrochemistry; single crystal surfaces; noble metals; CO oxidation; bisulfate adsorption;

D O I：

10.2298/JSC0609945M

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Infrared spectroelectrochemistry is the leading technique for in situ investigation of electrode - solution interfaces because it can both identify the species adsorbed at the metal/solution interface, and quantitatively follow their reaction and kinetic behavior. The unique capabilities of the method have been demonstrated by selective examples, including the identification of preferentially adsorbed species on single crystal surfaces of noble metals with hexagonal symmetry, and electrochemical oxidation of CO on bare and Pt-decorated single crystal Ru surfaces.

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收藏

页码：945 / 948

页数：4

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