Synthesis of a new C32H12 bowl-shaped aromatic hydrocarbon:: Acenaphtho[3,2,1,8-ijklm]diindeno[4,3,2,1-cdef:1′,2′,3′,4′-pqra]triphenylene

被引:19
作者
Marcinow, Z [1 ]
Grove, DI
Rabideau, PW
机构
[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA
[2] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA
关键词
D O I
10.1021/jo025645r
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The flash vacuum pyrolysis (FVP) of 1,2-bis(2-bromophenyl)-4,9-dibromocorannulene leads to a new C32H12 buckybowl.
引用
收藏
页码:3537 / 3539
页数:3
相关论文
共 14 条
[1]   1,6,7,10-TETRAMETHYLFLUORANTHENE - SYNTHESIS AND STRUCTURE OF A TWISTED POLYNUCLEAR AROMATIC HYDROCARBON [J].
BORCHARDT, A ;
HARDCASTLE, K ;
GANTZEL, P ;
SIEGEL, JS .
TETRAHEDRON LETTERS, 1993, 34 (02) :273-276
[2]   Synthesis of a new C32H12 bowl-shaped aromatic hydrocarbon [J].
Clayton, MD ;
Rabideau, PW .
TETRAHEDRON LETTERS, 1997, 38 (05) :741-744
[3]   NOVEL SYNTHESIS OF THE ANGULAR [3]PHENYLENE (TERPHENYLENE) BY COBALT-CATALYZED CYCLIZATION OF BIS(2-ETHYNYLPHENYL)ETHYNE - A MOLECULE WITH AN INTERNAL CYCLOHEXATRIENE RING [J].
DIERCKS, R ;
VOLLHARDT, KPC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (03) :266-268
[4]   Lowering inversion barriers of buckybowls by benzannelation of the rim:: Synthesis and crystal and molecular structure of 1 2-dihydrocyclopenta[b,c]dibenzo[g,m]corannulene [J].
Marcinow, Z ;
Sygula, A ;
Ellern, A ;
Rabideau, PW .
ORGANIC LETTERS, 2001, 3 (22) :3527-3529
[5]   Synthetic studies directed towards bucky-balls and bucky-bowls [J].
Mehta, G ;
Rao, HSP .
TETRAHEDRON, 1998, 54 (44) :13325-13370
[6]   Buckybowls: Polynuclear aromatic hydrocarbons related to the buckminsterfullerene surface [J].
Rabideau, PW ;
Sygula, A .
ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (05) :235-242
[7]   Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions:: A simple synthesis of dibenzo[a,g]corannulene [J].
Reisch, HA ;
Bratcher, MS ;
Scott, LT .
ORGANIC LETTERS, 2000, 2 (10) :1427-1430
[8]   Geodesic polyarenes with exposed concave surfaces [J].
Scott, LT ;
Bronstein, HE ;
Preda, DV ;
Ansems, RBM ;
Bratcher, MS ;
Hagen, S .
PURE AND APPLIED CHEMISTRY, 1999, 71 (02) :209-219
[9]   Synthesis and characterization of a C36H12 fullerene subunit [J].
Scott, LT ;
Bratcher, MS ;
Hagen, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (36) :8743-8744
[10]   THERMAL REARRANGEMENTS OF AROMATIC-COMPOUNDS .14. CORANNULENE - A CONVENIENT NEW SYNTHESIS [J].
SCOTT, LT ;
HASHEMI, MM ;
MEYER, DT ;
WARREN, HB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7082-7084