Preparation and characterization of methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate

被引：4

作者：

Herron, BF ^{[1
]}

Bagby, MO ^{[1
]}

Isbell, TA ^{[1
]}

Byrdwell, WC ^{[1
]}

Plattner, R ^{[1
]}

Weisleder, D ^{[1
]}

机构：

[1] USDA ARS,NATL CTR AGR UTILIZAT RES,PEORIA,IL 61604

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1997年 / 74卷 / 03期

基金：

美国国家卫生研究院;

关键词：

allylic amination; methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate; methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate; bis(N-p-toluenesulfonyl) sulfodiimide; methyl oleate;

D O I：

10.1007/s11746-997-0128-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Allylic amination of methyl oleate with bis(N-p-toluenesulfonyl) suliodiimide results in a mixture of methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate in 58% yield. These novel products were isolated and characterized by nuclear magnetic resonance,infrared spectroscopy, mass spectrometry, and melting point. The reaction was analyzed by high performance liquid chromatography and thin-layer chromatography.

引用

页码：229 / 234

页数：6

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