The first total synthesis of (+/-)-demethyl salvicanol

被引：21

作者：

Wang, XC ^{[1
]}

Pan, XF ^{[1
]}

Cui, YX ^{[1
]}

Chen, YZ ^{[1
]}

机构：

[1] LANZHOU UNIV,NATL LAB APPL ORGAN CHEM,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

TETRAHEDRON | 1996年 / 52卷 / 32期

关键词：

D O I：

10.1016/0040-4020(96)00604-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Demethyl salvicanol, a novel rearranged 9(10-->20)-abeo-8, 11, 13-triene diterpene, has been synthesize for the first time. The zinc-promoted coupling reaction of benzyl bromide with ketone and the alkylation of ketone with iodide are the key steps. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：10659 / 10666

页数：8

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