Reaction of 1-alkyn-5-ols with tetrahydrofuran-tungsten pentacarbonyl induces cyclization to the corresponding tungsten dihydropyranylidene carbenes. These carbenes can be converted into alpha-stannyl dihydropyrans upon reaction with tributyltin triflate and triethylamine. This strategy provides the first general preparation of six-membered ring oxacarbenes of the group VI metals, and a novel synthesis of alpha-stannyl dihydropyrans from acyclic compounds. Copyright (C) 1996 Elsevier Science Ltd
机构:
UNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCEUNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE
PARLIER, A
;
RUDLER, H
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机构:
UNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCEUNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE
机构:
UNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCEUNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE
PARLIER, A
;
RUDLER, H
论文数: 0引用数: 0
h-index: 0
机构:
UNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCEUNIV PARIS 06,CHIM ORGAN LAB,UNITE 408,T-44,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE