Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications

被引：950

作者：

Lin, Zu-Jin ^{[1
]}

Lu, Jian ^{[1
]}

Hong, Maochun ^{[1
]}

Cao, Rong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 16期

关键词：

CARBON-DIOXIDE CAPTURE; SUPERMOLECULAR BUILDING-BLOCKS; SELECTIVE CO2 CAPTURE; SINGLE-CRYSTAL TRANSFORMATION; INFINITE POLYMERIC FRAMEWORKS; COORDINATION POLYMERS; POROUS MATERIALS; GAS-ADSORPTION; POLYHEDRAL FRAMEWORKS; NANOPOROUS MATERIALS;

D O I：

10.1039/c3cs60483g

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Metal-organic frameworks (MOFs), also known as coordination polymers (CPs), are crystalline materials constructed from metal ions or clusters bridged by organic ligands to form one-, two-, or three-dimensional infinite networks. In contrast with the prolific production of MOFs based on rigid ligands (RL-MOFs), the design, syntheses and applications of MOFs based on flexible ligands (FL-MOFs) are somewhat overlooked. Although sacrificing a measure of control, the use of flexible ligands may provide unique opportunities to obtain novel crystalline framework materials exhibiting desirable attributes. In this review, emphasis has been placed on the design and the structural diversity of FL-MOFs. Homochiral FL-MOFs and dynamic frameworks induced by flexible ligands are also briefly outlined. An overview is also shown for the applications of FL-MOFs as platforms for gas adsorption, heterogeneous catalysis, proton conduction etc.

引用

页码：5867 / 5895

页数：29

共 252 条

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