Electrochemistry of C-82: Relationship to metallofullerene electrochemistry

被引:15
作者
Burbank, PB [1 ]
Gibson, JR [1 ]
Dom, HC [1 ]
Anderson, MR [1 ]
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV, DEPT CHEM, BLACKSBURG, VA 24061 USA
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 417卷 / 1-2期
关键词
C-82; metallofullerenes; electrochemistry; square-wave voltammetry;
D O I
10.1016/S0022-0728(96)01015-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Square-wave voltammetry of C-82 in pyridine solutions containing 0.10 M tetra-n-butyl ammonium perchlorate indicates that C-82 is reduced in four one-electron steps prior to the onset of electrolyte decomposition. The first reduction occurs at potentials positive of the reported first reduction potentials of other empty cage fullerenes, and at approximately the same reported potential for the first reduction of the endohedral metallofullerenes La@C-82 and Y@C-82. No oxidations were observed for the C-82 under these conditions.
引用
收藏
页码:1 / 4
页数:4
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